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I've received a some questions about exp 2 report.<br>
<br>
3) Discussion Section:<br>
<br>
It's quite possible most of you didn't get the correct formula
following the<br>
correct procedure. Multiplying by a factor to get whole number
subscripts<br>
might not give you a reasonable formula (within 0.1 of a whole
number).<br>
For instance it's unlikely to have something like Pb<sub>12</sub>O<sub>21</sub>
for an empirical<br>
formula for an ionic compound. Generally speaking, the most
positive<br>
charges (oxidation numbers) wouldn't exceed +8 and the most
negative<br>
wouldn't exceed -3. So what should you do?<br>
<br>
You should discuss whether your formula is reasonable. How do
you know?<br>
I've discussed what the normal charges for representative
metals are based on<br>
what group they're in. Group 3A (13) metals are usually +3 (Al
is always +3)<br>
but can be +1. Group 5A would be +5 or +3. I discussed lead,
Pb, in lecture<br>
and stated it is +2 or +4. If you don't see the pattern, the
charges for the<br>
representative metals in groups 3A-6A equals the group # or
(group # - 2).<br>
<br>
Based on this you should be able to predict the normal charges
for Sn. That will<br>
allow you to predict the most likely compounds for Sn and O.
Then look at your<br>
original ratio before you multiplied by the factor you used to
get the whole number<br>
ratio. Address why you might not have obtained the correct
ratio?<br>
<br>
To give an example, iron can form a +2 and +3 ion. This would
give FeO and<br>
Fe2O3. The Fe2O3 will result as the iron is oxidized over time
and converts from<br>
Fe to Fe^2+ (it's usually oxidation state in solution, at least
initially) and then to<br>
Fe^3+. This is particularly true when there's a greater amount
of oxygen available<br>
to react with the iron.<br>
<br>
If you've already turned in the report you can "fix" things if
you like and turn it in<br>
again. The TA will grade the most recent submission.<br>
<br>
Dr. Zellmer<br>
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